基于支持向量机的环境γ剂量率模型

核电厂外围环境辐射连续监测系统获取地表γ剂量率,当剂量率超过预先规定的阈值时,系统会发出警告。但氡子体影响、系统噪声造成的数值不稳定、剂量率具有周期性的变化均会使数据出现波动从而造成无效的报警。为辨别剂量率上升的原因,建立了支持向量机模型对环境剂量率超过阈值的原因进行分类,考察了不同参数对模型精度的影响。通过2000组以上历史数据验证,结果表明,该模型能对环境γ剂量率超过阈值的原因进行准确分类,准确率达98%以上。     

Characterization and Properties of Nickel Aluminide Nanocrystals in an Alumina Layer for Nonvolatile Memory Applications

Intermetallic nanocrystal memory devices with nickel aluminide nanocrystals in the electron-trapping layer and an alumina layer as the blocking layer were prepared on the surface of oxidized silicon substrates by sputter-coating of Ni and Al₂O₃ in sequence, followed by an annealing procedure. Several aluminide nanocrystal memory devices are reported. The effect of annealing at 900°C on the memory properties was investigated. Intermetallic nanocrystals were identified by high-resolution transmission electron microscopy and x-ray photoelectron spectroscopy as Ni₂Al₃ with sizes of 15–20 nm. The results showed that a sixfold increase (0.37 V to 2.34 V) in the memory window could be achieved after annealing for the optimal time of 3 min.     

Reader Coverage Analysis for Multi-Carrier Passive UHF RFID Systems

Applications of passive radio frequency identification (RFID) systems have gained considerable attentions in recent years. Because a passive tag must obtain its operating power from a continuous wave transmitted from a reader in a conventional RFID system, reader coverage is limited. Thus, expanding reader coverage is a current goal in RFID research. In this work, passive tags are provided with additional operating power via continuous waves in multiple frequency bands. In an interrogation region, continuous wave emitters, which provide additional operating power to passive tags, are deployed according to the base station configuration in a cellular phone system. Because transmission power of continuous wave emitters must consider the reader command demodulation constraint and minimum operating power required by a tag, transmission power of continuous wave emitters must be chosen carefully. A method for analyzing reader coverage in multi-carrier passive UHF RFID systems is derived in this work. Assuming all tags are uniformly distributed in an interrogation region, the optimal continuous wave emitter transmission power that achieves the largest reader coverage can be analytically determined. Simulation results verify that continuous wave emitters with suitable transmission power expand reader coverage in a multi-carrier passive UHF RFID system. Additionally, adjusting reader power in the forward (reader-to-tag) link duration can loosen the reader command demodulation constraint and thereby further expand reader coverage.     

Toward multiple maximum power point estimation of photovoltaic systems based on semiconductor theory

Environmental conditions, such as temperature, non‐uniform irradiation, and solar shading, deeply affect the characteristics of photovoltaic (PV) modules in PV‐assisted generation systems. Several local maximum power points (MPPs) are found in the power–voltage curve of PV systems constructed by series/parallel‐connected PV modules under partially shaded conditions. The characteristics of PV systems change unpredictably when multiple MPPs occur, so the actual MPP tracking (MPPT) becomes a difficult task. Conventional MPPT methods for the PV systems under partially shaded conditions cannot quickly find the actual MPP such that the optimal utilization of PV systems cannot be achieved. Based on the p–n junction semiconductor theory, we develop a multipoint direct‐estimation (MPDE) method to directly estimate the multiple MPPs of the PV systems under partially shaded conditions and to cope with the mentioned difficulties. Using the proposed MPDE method, the multiple MPPs of the PV systems under partially shaded conditions can be directly determined from their irradiated current–voltage and power–voltage characteristic curves. The performances of the proposed MPDE method are evaluated by examining the characteristics of multiple MPPs of PV systems with respect to different shading strengths and numbers of the shaded PV modules and also tested using the field data. The experimental results demonstrate that the proposed MPDE method can simply and accurately estimate the multiple MPPs of the PV systems under partially shaded conditions. The optimization of MPP control models and the MPPT for PV systems could be achieved promisingly by applying the proposed method. Copyright © 2014 John Wiley & Sons, Ltd.     

Novel H.264/AVC entropy coding mode decision

In this work, we propose a novel entropy coding mode decision algorithm to balance the tradeoff between the rate-distortion (R-D) performance and the entropy decoding complexity for the H.264/AVC video coding standard. Context-based adaptive binary arithmetic coding (CABAC), context-based adaptive variable length coding (CAVLC), and universal variable length coding (UVLC) are three entropy coding tools adopted by H.264/AVC. CABAC can be used to encode the texture and the header data while CAVLC and UVLC are employed to encode the texture and the header data, respectively. Although CABAC can provide better R-D performance than CAVLC/UVLC, its decoding complexity is higher. Thus, by taking the entropy decoding complexity into account, CABAC may not be the best tool, which motivates us to examine the entropy coding mode decision problem in depth. It will be shown experimentally that the proposed mode decision algorithm can help the encoder generate the bit streams that can be decoded at much lower complexity with little R-D performance loss.     

Hierarchical B-picture mode decision in H.264/SVC

To enable robust video transmission over heterogeneous networks, the hierarchical B-picture prediction structure is employed in the state-of-the-art video coding standard H.264/SVC, aiming to produce scalable bitstreams with various frame rates. However, the exhaustive mode decision process with the hierarchical B-picture structure increases the computational complexity of H.264/SVC encoding dramatically. In this paper, a fast mode decision algorithm is proposed to speed up H.264/SVC encoding with the hierarchical B-picture structure, which is achieved by utilizing macroblock (MB) features, correlation of temporal–spatial neighboring MBs, and the discrepant characteristics of hierarchical layers. Extensive experimental results demonstrate that the proposed algorithm is able to reduce the encoding time of H.264/SVC significantly for video sequences with a wide range of resolutions, and meanwhile the video quality and compression ratio are well preserved.     

Cryptanalysis of Hsiang‐Shih's authentication scheme for multi‐server architecture

From user point of view, password‐based remote user authentication technique is one of the most convenient and easy‐to‐use mechanisms to provide necessary security on system access. As the number of computer crimes in modern cyberspace has increased dramatically, the robustness of password‐based authentication schemes has been investigated by industries and organizations in recent years. In this paper, a well‐designed password‐based authentication protocol for multi‐server communication environment, introduced by Hsiang and Shih, is evaluated. Our security analysis indicates that their scheme is insecure against session key disclosure, server spoofing attack, and replay attack and behavior denial. Copyright © 2010 John Wiley & Sons, Ltd.     

Confined Ferroelectric Properties in Poly(Vinylidene Fluoride‐co‐Chlorotrifluoroethylene)‐graft‐Polystyrene Graft Copolymers for Electric Energy Storage Applications

Dielectric polymer film capacitors having high energy density, low loss and fast discharge speed are highly desirable for compact and reliable electrical power systems. In this work, we study the confined ferroelectric properties in a series of poly(vinylidene fluoride‐co‐chlorotrifluoroethylene)‐graft‐polystyrene [P(VDF‐CTFE)‐g‐PS] graft copolymers, and their potential application as high energy density and low loss capacitor films. Thin films (ca. 20 μm) are prepared by different processing methods, namely, hot‐pressing or solution‐casting followed by mechanical stretching at elevated temperatures. After crystallization‐induced microphase separation, PS side chains are segregated to the periphery of PVDF crystals, forming a confining interfacial layer. Due to the low polarizability of this confining PS‐rich layer at the amorphous–crystalline interface, the compensation polarization is substantially decreased resulting in a novel confined ferroelectric behavior in these graft copolymers. Both dielectric and ferroelectric losses are significantly reduced at the expense of a moderate decrease in discharged energy density. Our study indicates that the best performance is achieved for a P(VDF‐CTFE)‐g‐PS graft copolymer with 34 wt‐% PS; a relatively high discharged energy density of approximately 10 J cm^?3 at 600 MV m^?1, a low dielectric loss (tanδ = 0.006 at 1 kHz), and a low hysteresis loop loss (17.6%) at 550 MV m^?1.     

Cu2O Nanocrystal‐Templated Growth of Cu2S Nanocages with Encapsulated Au Nanoparticles and In‐Situ Transmission X‐ray Microscopy Study

Cubic and octahedral Cu₂O nanocrystals and Au–Cu₂O core–shell heterostructures are used as sacrificial templates for the growth of Cu₂S nanocages and Au–Cu₂S core–cage structures. A rapid sulfidation process involving a surface reaction of Cu₂O nanocrystals with Na₂S, followed by etching of the Cu₂O cores with HCl solution for ≈5 sec, results in the fabrication of Cu₂S cages with a wall thickness of 10–20 nm. Transmission electron microscopy characterization reveals the formation of crystalline walls and the presence of ultrasmall pores with sizes of 1 nm or less. Formation of Cu₂O–Cu₂S core–shell structures and their conversion into Cu₂S cages is verified by UV–vis absorption spectroscopy. X‐ray photoelectron spectra further confirm the composition of the cages as Cu₂S. The entire hollowing process via the Kirkendall effect is recorded using in‐situ transmission X‐ray microscopy. After shell formation, continuous ionic diffusion removes the interior Cu₂O. Intermediate structures with remaining central Cu₂O portions and bridging arms to the surrounding cages are observed. The nanocages are also shown to allow molecular transport: anthracene and pyrene penetration into the cages leads to enhanced fluorescence quenching immediately upon adsorption onto the surfaces of the encapsulated gold nanocrystals.     

Polymer‐Stabilized Chromonic Liquid‐Crystalline Polarizer

Robust coatable polarizer is fabricated by the self‐assembly of lyotropic chromonic liquid crystals and subsequent photo‐polymerizing processes. Their molecular packing structures and optical behaviors are investigated by the combined techniques of microscopy, scattering and spectroscopy. To stabilize the oriented Sunset Yellow FCF (H‐SY) films and to minimize the possible defects generated during and after the coating, acrylic acid (AA) is added to the H‐SY/H₂O solution and photo‐polymerized. Utilizing cross‐polarized optical microscopy, phase behaviors of the H‐SY/H₂O/AA solution are monitored by varying the compositions and temperatures of the solution. Based on the experimental results of two‐dimensional wide angle X‐ray diffraction and selected area electron diffraction, the H‐SY crystalline unit cell is determined to be a monoclinic structure with the dimensions of a = 1.70 nm, b = 1.78 nm, c = 0.68 nm, α = β = 90.0° and γ = 84.5°. The molecular arrangements in the oriented H‐SY films were further confirmed by polarized Fourier‐transform infrared spectroscopy. The polymer‐stabilized H‐SY films show good mechanical and chemical stabilities with a high polarizability. Additionally, patterned polarizers are fabricated by applying a photo‐mask during the photo‐polymerization of AA, which may open new doors for practical applications in electro‐optic devices.